Oxidation of 17-methylene steroids by thallium(III) and mercury(II) acetates
โ Scribed by G. Ortar; M.P. Arpiani; A. Romeo
- Book ID
- 118978252
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 425 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0039-128X
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๐ SIMILAR VOLUMES
## Abstract The oxidative cleavage of some aliphatic ketoximes by thallium(III) acetate was studied in the temperature range of 20โ40ยฐC. The reactions were followed by determination of the rates of disappearance of thallium(III) acetate for variations in [substrate], [Tl(III)], [H^+^], ionic streng
Thallium triacetate in acetic acid gave clean regeneration of both aldehydes and ketones from their toluene-p-sulphonylhydrazones. The reagent gave N-aroyl-N' -acetyl-NV-phenylhydrazines from aromatic aldehyde phenylhydrazones without prior dehydrogenation to nitrilimine intermediates. Considerable