Oxidation of 1-O-(alk-1-enyl)-2,3-di-O-acylglycerols: Models for plasmalogen oxidation
✍ Scribed by Thomas A. Foglia; Edwin Nungesser; William N. Marmer
- Book ID
- 112773596
- Publisher
- Springer-Verlag
- Year
- 1988
- Tongue
- English
- Weight
- 555 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0024-4201
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📜 SIMILAR VOLUMES
2-(AIk-l-enyl)-l,3,2-diazaphospholidine 2-oxides 4, containing the trans-N,N'-dihenzylcyclohexane-l,2diamine chiral auxiliary, may he prepared by palladium(0)-mediated coupling of the phosphorous acid derivative 3 with alkenyi halides. The X-ray crystal structure of the prop-l-enyl compound 4b has b
## Abstract The anodic oxidation of (±)‐1,2‐__O__‐isopropylideneglycerol at a silver/silver oxide electrode with a controlled potential of +0.9 V vs. SCE in 2.5 N sodium hydroxide affords sodium (±)‐2,3‐__O__‐isopropylideneglycerate in a yield of 75%. Treatment of this salt with dimethyl sulfate an