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Oxidation mechanism of dimethyl sulfoxide (DMSO) by OH radical in liquid phase

✍ Scribed by Baptista, Leonardo; Clemente da Silva, Edilson; Arbilla, Graciela


Book ID
120878301
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
827 KB
Volume
10
Category
Article
ISSN
1463-9076

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanism of oxidation of d
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t