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Oxidation-Induced Rearrangement from a nido - to a closo -Ruthenacyclopentadiene

โœ Scribed by Takao, Toshiro; Inagaki, Akiko; Imamura, Tsubomi; Suzuki, Hiroharu

Book ID
121334483
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
188 KB
Volume
25
Category
Article
ISSN
0276-7333

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## Abstract A sensitive cluster: The labile rhodathiaborane [(PPh~3~)~2~(H)โ€__nido__โ€RhSB~9~H~9~(NC~5~H~5~)] combines the redox and coordinative flexibility of the {(PPh~3~)~2~(H)Rh} fragment with the capability of the 11โ€vertex rhodathiaborane cluster to undergo oxidative __nido__โ€toโ€__closo__ tra