The elevated-temperature oxidation behaviour of a TiBN coating on a plasma-nitrided hot-work tool steel (DIN 1.2367) by means of plasma-assisted chemical vapour deposition (PACVD) was investigated under the condition where a coated die would be preheated prior to being mounted on the press for aluminium extrusion. The TiBN coating was found to possess good resistance to oxidation up to 400 Β°C. Rapid oxidation started to occur at 450 Β°C. Radio frequency glow discharge optical emission spectroscopy (rf-GDOES) indicated that the oxidised layer was thickened from 100 nm to 1.0 ΞΌm, as the soaking time at 500 Β°C was prolonged from 2 to 16 h, which was attributed to the high temperature that promoted the penetration of oxygen into the coating. rf-GDOES also showed that boron initially in the coating vanished from the oxidised layer when the temperature was 450 Β°C or higher. X-ray diffractometry confirmed that the oxidised layer was composed mainly of TiO 2 . SEM revealed that the TiO 2 layer was pulverised, leaving many microcracks and cavities, as a result of the losses of boron oxide and nitrogen. The rapid oxidation at above 450 Β°C was attributed to the pulverised TiO 2 layer that was unable to hinder the diffusion of oxygen into the coating. It is therefore recommended to apply a protective gas during the preheating of the TiBN-coated die for aluminium extrusion. Alternatively, an advanced TiBN coating with enhanced resistance to oxidation must be developed, which will be conducive to its application for aluminium extrusion dies.