Resonance Raman spectroscopy has been used to study the oxidation of ferrocene in zeolite cavities. The formation of the ferricenium cation in the presence of oxygen is strongly influenced by the co-cations present inside the zeohte cavities.
Oxidation and reduction of silver in zeolite Y: a structural study
β Scribed by L.R. Gellens; W.J. Mortier; J.B. Uytterhoeven
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 559 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0144-2449
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Encapsulation of two different Mn(II)salen complexes within the supercavities of zeolite Y was accomplished by means of two established synthetic routes and they were unequivocally characterized by spectroscopic techniques [Fourier transform infrared, diffuse reflectance and electron paramagnetic re
## Addition of trimethylphosphine to a rapidly dehydrated copper Y zeolite resulted in the immediate reduction of the copper to the univalent oxidation state. After a brief evacuation, addition of oxygen caused the instantaneous oxidation of the &(I) ions and the complexing ligands. It is proposed t