Oxidation and Decomposition Kinetics of Thiourea Oxides
โ Scribed by Gao, Qingyu; Liu, Bing; Li, Lianhe; Wang, Jichang
- Book ID
- 120799896
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 99 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
The stoichiometry and kinetics of the oxidation of thiourea (SC(NH2)z) by chlorine dioxide (ClOz) have been studied by uv-vis spectrophotometry using conventional and stopped-flow mixing techniques at 25.0 ? O.l"C, pH 0.3-4.8. In high acid and initial 10 : 1 molar ratio of thiourea to chlorine dioxi
It may be noted that in a relatively low pH range only -NH2 and -COOgroups are involved in the formation of the blue complex v but as the pH is raised the -OH group also participates in complex formation and the colour of the solution changes to violet.