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Oxetene: synthesis and energetics of electrocyclic ring opening

โœ Scribed by Martino, Philip C.; Shevlin, Philip B.


Book ID
120008234
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
260 KB
Volume
102
Category
Article
ISSN
0002-7863

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## 2,4,4-Trimethyl-2-cyclobutenone ( 9 ) 3-Ethoxy-2,4,4-trimethylcyclobutanone (19.0g, 0.1 2mol) in ether (290ml) was mixed to a paste with neutral AI,O, (230g); after 24h the mixture was poured onto a column of dry A1,0, (100g) and eluted with ether (800ml). The solvent was removed by fractional