Radical mediated synthesis of N-acetyl-d
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Gilles Rubinstenn; Jacques Esnault; Jean-Maurice Mallet; Pierre Sinaÿ
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Article
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1997
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Elsevier Science
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English
⚖ 671 KB
The C-disaccharide {(X-D-GalNAc-C-(I~4)-13-D-GIc-OMe} and its interglycosidic 13 anomer were synthesized by radical coupling of phenyl 2-amino-3,4,6-tri-O-benzyl-2-deoxy-l-seleno-0~-D-galactopyranoside onto methyl 2,6-di-O-benzyl-4-deoxy-4-C-methylene-13-D-xylo-hexopyranoside, which are temporarily