Oxazolidine-2-thiones and Thiazolidine-2-thiones as Nucleophiles in Intermolecular Michael Additions
β Scribed by Munive, Laura; Rivas, Veronica M.; Ortiz, Aurelio; Olivo, Horacio F.
- Book ID
- 126058127
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 314 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Alkoxycarbonyloxy radicals from ally1 and homoallyl alcohols cyclize in an exe fashion to give, respectively, 3-substituted 1,Zdiol camonates and 4-substituted 1,3diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of gl
1,3-Oxazoline-(OXT) and 1,3-oxazolidine-2-thiones (OZT) can undergo direct Stille and Suzuki cross-coupling reactions under microwave activation to produce 2-aryloxazoles and 2-aryloxazolines in reasonable to good yields.