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Oxazoles Formation During O-Alkylation of Isonitroso-naphthols. X-Ray Structure of [1,2]Naphthoquinone 1-[O-(4-tert-Butyl-benzyl)-oxime] and 2-(4-tert-Butyl-phenyl)naphth[1,2-d]oxazole.

✍ Scribed by Paola Astolfi; Patricia Carloni; Riccardo Castagna; Lucedio Greci; Corrado Rizzoli; Pierluigi Stipa


Publisher
John Wiley and Sons
Year
2005
Weight
16 KB
Volume
36
Category
Article
ISSN
0931-7597

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Oxazoles formation during O-alkylation o
✍ Paola Astolfi; Patricia Carloni; Riccardo Castagna; Lucedio Greci; Pierluigi Sti 📂 Article 📅 2004 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 70 KB

## Abstract 1‐Nitroso‐2‐naphthol and 2‐nitroso‐1‐naphthol, both in the isonitroso form, react with benzyl bromides in THF and in the presence of triethylamine affording, in low yields, the corresponding __O__‐benzyl oximes and 2‐aryl naphthoxazoles in a 1:1 ratio, approximately. The structures of _