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Oxalyl halides: Part II. Vibrational spectra and assignments for oxalyl fluoride and oxalyl chloride fluoride

โœ Scribed by J.L. Hencher; G.W. King


Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
625 KB
Volume
16
Category
Article
ISSN
0022-2852

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Vibrational Spectra of cis and trans Oxa
โœ Stefan Sander; Helge Willner; Leonid Khriachtchev; Mika Pettersson; Markku Rรคsรคn ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 103 KB

A cis/trans equilibrium mixture of matrix-isolated oxalyl fluoride was irradiated with a narrowband tunable IR source in the 2 (CO) spectral region (3680 -3710 cm ฯช1 ). Rotamerization of cis into trans and vice versa was achieved (even site selective) by selective IR pumping. The experiments strongl