Oxalic Acid-Catalyzed Reaction of Alcohols with NaSCN: The Effects of Additives NaI and I2
โ Scribed by Hideyoshi Miyake; Yuichi Nakao; Mitsuru Sasaki
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 35 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
๐ SIMILAR VOLUMES
โขโขs proceeded with almost equal frequency at both C=-C (Michael addition) and C=O (ring opening) groups; reaction with secondary and tertiary alcohols resulted in a modest elevation in Michael addition. Michael addition was not observed in reactions with 4, 4-dimethyl-2-isopropenyl-5(4H)oxazolone.
Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature. I 2 generated in situ from Fe(NO 3 ) 3 โข9H 2 O/NaI also catalyzed the formylation of the alcohols under solvent-free conditions. Thi