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Overtone spectroscopy of acetyl compounds. Inequivalent ch oscillators and substituent effects of the carbonyl group

✍ Scribed by Ryoichi Nakagaki; Ichiro Hanazaki


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
506 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis


CH stretching overtone spectra of acetyl compounds are measured in the liquid phase. A doublet structure is commonly observed in the overtone spectra of acetyl CH stretching vibrations and is attributed to the sterically inequivalent orientations of methyl CH bonds. Substituent effects exerted by the carbonyl group are discussed.