Overall view of the use of chiral platinum(II) complexes as chiral derivatizing agents (CDAs) for the enantiodiscrimination of unsaturated compounds by 195Pt NMR

✍ Scribed by Gloria Uccello-Barretta; Raffaella Bernardini; Federica Balzano; Piero Salvadori

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 138 KB
• Volume: 14
• Category: Article
• ISSN: 0899-0042
• DOI: 10.1002/chir.10073

✦ Synopsis

The use of organometallic CDAs based on ethene-platinum(II) complexes, covalent cis- and trans-dichloro(Am)(ethylene)platinum(II), and ionic PtCl(3)(C(2)H(4))AmH, containing primary and secondary amines, for the (195)Pt NMR enantiodiscrimination of chiral unsaturated compounds is reviewed.