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Outer Sphere Metal-to-Ligand Charge Transfer in Organometallic Ion Pairs

✍ Scribed by Lucia, Lucian A.; Abboud, Khalil; Schanze, Kirk S.


Book ID
126435907
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
350 KB
Volume
36
Category
Article
ISSN
0020-1669

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Mechanistic roles of metal-to-ligand cha
✍ Antonı́n Vlček Jr. πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 314 KB

Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s