๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Outer-sphere and inner-sphere interactions in the formation of metal-ion nitrate complexes

โœ Scribed by Donald F.C. Morris; John D. MacCarthy; Robert J. Newton

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
340 KB
Volume
23
Category
Article
ISSN
0013-4686

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โœฆ Synopsis

A liquid-liquid distribution method using radioactive tracers has been employed to determine stoichiometric stability constants for the formation of mononitrato-complexes of Mn" and Cd". In each system only quite weak complexing is found. With Mn *+-NO; the interaction between the two ions is of outer-sphere kind. whereas in the case of Cd '+-NO; both outer and inner sphere species appear lo be formed. These concIusions are compatible with Raman spectral evidence.

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