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Out-Basicity of 1,8-bis(dimethylamino)naphthalene: the experimental and theoretical challenge

✍ Scribed by Ozeryanskii, Valery A.; Pozharskii, Alexander F.; Antonov, Alexander S.; Filarowski, Alexander

Book ID: 121425758
Publisher: Royal Society of Chemistry
Year: 2014
Tongue: English
Weight: 968 KB
Volume: 12
Category: Article
ISSN: 1477-0520
DOI: 10.1039/C3OB41986J

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## Abstract The ESCA spectrum of protonated 1,8‐bis‐(dimethylamino) naphthalene (“proton sponge”) (I) has been recorded in the region of N1s binding energies. The results indicate that IH^+^ possesses an __unsymmetrical__ NH…︁N hydrogen bridge.