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Osmotic backwash mechanism of reverse osmosis membranes

โœ Scribed by Abraham Sagiv; Neta Avraham; Carlos G. Dosoretz; Raphael Semiat


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
794 KB
Volume
322
Category
Article
ISSN
0376-7388

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โœฆ Synopsis


A new osmotic backwash (BW) model for reverse osmosis (RO) membranes was developed for conditions of no applied pressures across the membrane. This analytical model has one adjustable parameter representing the coefficient of a linearized convection term in the general convection-diffusion equation. An experimental RO/BW system was used for 12 data sets to verify the proposed BW model and illustrate its predictability. Results show deviations of the model from the data within a range of 5-15%. The described dilution mechanism of the feed concentration polarization (CP) layer is based on RO originated concentrated layer detachment from the membrane surface followed by its gradual dilution.

The understanding gained in this research may be applied to automatic RO/BW cleaning cycles. A dominant RO parameter of the BW process is the RO initial driving force-the concentration difference across the membrane. Other RO process parameters -applied pressure and feed flow rate -have lesser effects. Both theoretical and experimental methods provide quantitative relationships between RO and BW variables that enable an understanding and control of the BW process.


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Small colloidal particles intermediate in size between suspended solids, and true dissolved solids have been causing serious problems to many reverse osmosis systems throughout the world, These tiny negatively charged particles become concentrated at the surface of the membrane during the R-Oprocess