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Oscillator strengths and ionisation cross sections for the absorption of CF2Cl2 in the UV and VUV spectral regions. A MQDO study

✍ Scribed by A.M Velasco; E Mayor; I Martı́n

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 205 KB
Volume: 376
Category: Article
ISSN: 0009-2614
DOI: 10.1016/s0009-2614(03)00962-x

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✦ Synopsis

Absorption oscillator strengths and photoionisation cross sections of CF 2 Cl 2 have been calculated with the molecular-adapted quantum defect orbital (MQDO) approach. The differential oscillator strengths for the different Rydberg series that constitute the ionisation channels of CF 2 Cl 2 from its ground state are reported. The MQDO differential oscillator strengths exhibit the expected continuity across the ionisation threshold. In addition, good agreement with experiment is found for the cross sections that correspond to the photoionisation from the (4b 1 þ 4b 2 ) valence MOÕs.

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