Oscillation reactions in the system: Metabolites of krebs cycle-Mn2+-KBrO3-H2SO4
✍ Scribed by J.Masełko T. Tłaczala; M. Czerwiński; J. Michałczyk; Z. Sikorski
- Book ID
- 104105920
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 483 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0006-3061
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✦ Synopsis
The appearance of oscillations & the Ksebs,kycre with metabolites such as oxaloacetic and citric acids has been contkmed experimentally in model systems utilizing hfn2+ as the catalyst and KBrOdH@O4 as the oxidant. Oscillations occur over a range of concentrations of substrate. The oscillation period also depends on the metabolite concentration. It has been found that malic acid and oxaloacetic acid constitute a coupled oscillator system. The experiments are discussed in relation to other metabolite cycles.
📜 SIMILAR VOLUMES
The title compound was studled m a strrrcd tank reactor, and Its state followed by the platmum and bromide electrode potcntlals The system exhibits chaotic osclllatlons resultrng from the exlstcnce of strange attractors Double and triple os-cdlatIons occur as a result of the ewstence of loops or def
The voltammetric behaviour of Mn 8+, Mn\*+ and mixtures of these ionic species in 15 N HBSOp on a smooth platinum micro-electrode with periodical renewal of the diffusion layer shows that the reduction occurs through the electro-active couple Mn\*+, Mn\*+. The value of the electron-transfer coeffici