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Oscillating reactions at metal electrodes in solid electrolytes

✍ Scribed by Jürgen Janek


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
589 KB
Volume
101-103
Category
Article
ISSN
0167-2738

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✦ Synopsis


The transfer of matter and charge across interfaces between two solids is generally related to processes of defect relaxation in the regions near the interface. A transfer rate which exceeds the rate of defect relaxation may lead to degradation of the interface, causing a feedback effect for the transfer itself. As a consequence, non-linear phenomena (dissipative structures) like periodic oscillations of the interfacial properties can occur under conditions far from equilibrium. Experimental examples are discussed.


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The adsorption of coumarin at solid meta
✍ L.K. Partridge; A.C. Tansley; A.S. Porter 📂 Article 📅 1967 🏛 Elsevier Science 🌐 English ⚖ 433 KB

The effect of coumarin on the "deposition potential" of a number of metals at solid metal surfaces has been compared with that at a dropping mercury electrode. These results have been used to interpret the adsorption of coumarin on different metal surfaces and to suggest that Tl+ and Pb\*+ ions are