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“Oscillating” Metallocene Catalysts: How Do They Oscillate?

✍ Scribed by Vincenzo Busico; Roberta Cipullo; Winfried P. Kretschmer; Giovanni Talarico; Michele Vacatello; Valeria Van Axel Castelli

Book ID: 101373733
Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 98 KB
Volume: 114
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3757(20020201)114:3<523::aid-ange523>3.0.co;2-y

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## Abstract Octahedral group 4 complexes of a new bulky tetradentate dithiodiphenolate {OSSO}‐type ligand that oscillate between two enantiomeric __C__~2~‐symmetric conformations are described. The dibenzyl Zr and Hf complexes led to active catalysts in propylene polymerization. Polypropylene havin