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Orthorhombic and monoclinic allotropes of cis-[PtCl2(PMePh2)2], cis-dichlorobis(methyldiphenylphosphine)platinum(II): structure analyses

✍ Scribed by Ho, K. C. ;McLaughlin, G. M. ;McPartlin, M. ;Robertson, G. B.


Book ID
114528181
Publisher
International Union of Crystallography
Year
1982
Weight
578 KB
Volume
38
Category
Article
ISSN
0567-7408

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Chiral platinum(II) complexes. Crystal a
✍ Maria H Johansson; Torsten MalmstrΓΆm; Ola F Wendt πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 120 KB

The reaction between trans-PtPhCl(SMe 2 ) 2 and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P2 1 with a=12.875(3), b=18.012(4), c= 13.864(3) A , , i = 109.71(3)Β°and Z =4. In CDCl 3 1 reacts with Ph 2 P(C 6 H 4 )CH 2 N(Me)(COEt) to give c