𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Orthometalation reactions in trifluoroacetate dirhodium(II) compounds. Molecular structure of Rh2(O2CCF3)2[(C6H4)PPh2]2·(PPh3)2·2(C7H8)

✍ Scribed by Francisco Estevan; Pascual Lahuerta; Eduardo Peris; M. Angeles Ubeda; Santiago García-Granda; Fermín Gómez-Beltrán; Enrique Pérez-Carreño; Gabriel González; Manuel Martínez

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
475 KB
Volume
218
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reaction of Rh2(μ2-O2CCH3)3[μ2-(C6H4)PMe
Reaction of Rh2(μ2-O2CCH3)3[μ2-(C6H4)PMePh](HO2CCH3)2 with triphenylphosphine: rearrangement of the metalated PMePh2 ligand and formation of a compound with a diphenylphosphinomethanide group in (P,C) coordination; crystal structure of [Rh2(μ2-O2CCH3)2{μ2-(CH2)PPh2}- {μ2-(C6H4)PPh2}(PPh3)]·2CH2Cl2
✍ Francisco Estevan; Santiago García-Granda; Pascual Lahuerta; Julio Latorre; Edua 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 628 KB
Synthesis of a New Multidentate Phosphan
Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4-1,2,4,5 − X-ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: [{RuCl2(PPh3)}2{C6H2(CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′}]
✍ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho