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Orthometalation of m-bis(dimethylaminomethyl)benzene: crystal structure and chemistry of trans-Rh(III)Cl2[C6H3(CH2NMe2)2-o,o'](H2O)

✍ Scribed by Van der Zeijden, Adolphus A. H.; Van Koten, Gerard; Luijk, Ronald; Vrieze, Kees; Slob, Cees; Krabbendam, Hendrik; Spek, Anthony L.


Book ID
120662394
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
853 KB
Volume
27
Category
Article
ISSN
0020-1669

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The preparation, crystal structure and magnetic properties of the title compound, (1,3-xylylenediammonium)auqatrichlorocuprate(II) chloride hydrate, have been determined. It is monoclinic, space group P2 1 /c, with a=12.711(2), b= 6.122(1), c=19.175(5) A , and i =96.72(2)Β°with V= 1481.6(5) A , 3 for