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Orthogonal Carbon Nanofibers by Template-Mediated Assembly of Discotic Mesophase Pitch

✍ Scribed by K.Q. Jian; H.-S. Shim; A. Schwartzman; G.P. Crawford; R.H. Hurt


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
178 KB
Volume
15
Category
Article
ISSN
0935-9648

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✦ Synopsis


Novel carbon nanofibers (see Figure) are synthesized by capillary impregnation of discotic mesophase pitch into nanochannel alumina. Heating and chemical etching produces nanofibers with a unique “orthogonal” arrangement of graphene layers. Unlike conventional nanofibers and ‐tubes, the graphene planes lie transverse to the fiber axis, which reflects the equilibrium state for the discotic precursor confined to nanocylindrical geometry.