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“ ortho -Wurster's Crowns”: Synthesis and Properties of a Novel Phenylenediamine-Based Redox-Active Macrocyclic Ligand

✍ Scribed by Sibert, John W.; Forshee, Philip B.


Book ID
127052472
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
72 KB
Volume
41
Category
Article
ISSN
0020-1669

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‘meta-Wurster's crowns’: The synthesis a
✍ John W. Sibert; Daniel J. Seyer; Greg R. Hundt 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 297 KB

meta-Wurster's crowns are a new class of hosts that incorporate the meta-phenylenediamine moiety within a macrocyclic framework. We have used a Pd-catalyzed amination procedure in the synthesis of representative m-Wurster's crown members containing aza-12-crown-4, aza-15-crown-5 and aza-18-crown-6 m