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Ortho-para Protonation of Toluene and Ethylbenzene in Super Acids

✍ Scribed by Dr. Dan Fǎrcaşiu; Dr. M. T. Melchior; Dipl.-Chem. Lynne Craine


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
337 KB
Volume
16
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Chemical shifts for tritons in the ortho
✍ D. Calvert; R. W. Martin; A. L. Odell 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB

## Abstract Chemical shifts for tritons in __ortho__, __meta__ and __para__ positions in toluene have been determined using a 64 MHz tritium NMR spectrometer. The order of shift is __meta__>__para__>__ortho__, whereas the calculated shift order for protons is __meta__>__ortho__>__para__.

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## Abstract Apolar aprotic solvents are particularly advantageous for investigating the intrinsic metasubstituent effect free from complications of specific solvent effects. A kinetic study for toluene‐phase proton transfers between __meta__‐Me, F, Cl, Br, I, OMe, OPh, COPh, CF~3~, CN, NO~2~, H ben