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ortho-Lithiation of S-tert-Butyl-S-phenylsulfoximines. New Route to Enantiopure Sulfinamides via a De-tert-Butylation Reaction.

✍ Scribed by Stephane Gaillard; Cyril Papamicael; Georges Dupas; Francis Marsais; Vincent Levacher


Publisher
John Wiley and Sons
Year
2005
Weight
37 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract The synthesis of primary amine end‐functional poly(__tert__‐butyl acrylate)s has been achieved by using the Gabriel reaction. Polymerization of __tert__‐butyl acrylate was first achieved by atom transfer radical polymerization using ethyl‐2‐bromoisobutyrate or paramethoxyphenyl‐2‐bromoi