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Ortho ester hydrolysis. The complete reaction mechanism

โœ Scribed by Ahmad, M.; Bergstrom, R. G.; Cashen, M. J.; Kresge, A. J.; McClelland, R. A.; Powell, M. F.

Book ID
121457158
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
412 KB
Volume
99
Category
Article
ISSN
0002-7863

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and the Wiberg bond order is 0.67. The natural charges are +OX7 on B and -1 .OO on N (vide supra, note signs). We conclude that the diorgano(pyrazoly1)boranes have similar geometries in solution and in the solid phase. Although symmetrical structures like 3 are involved in the degenerate rearrangem