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Ortho effects in organic molecules on electron impact. 14—Concerted and stepwise ejections of SO2 and N2 from N-arylidene 2-nitrobenzenesulphenamides

✍ Scribed by D. V. Ramana; N. Sundaram; M. George

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
324 KB
Volume
22
Category
Article
ISSN
1076-5174

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Double oxygen migration to sulphur from the ortho-nitro group leading to eliminations of SO2 and 'S02H from the molecular ions and single oxygen transfer to the olefinic double bond in the sidechain giving rise to the most abundant ion at m/z 138 have been observed in 2-nitrophenyl styryl sulphides