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ortho- and para-Thioquinonoid π-Complexes: First Synthesis, Reactivity, and Crystal Structure Determination

✍ Scribed by Jamal Moussa; Marie Noelle Rager; Kamal Boubekeur; Hani Amouri


Book ID
102167081
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
174 KB
Volume
2007
Category
Article
ISSN
1434-1948

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✍ Gerd W. Rabe; Norbert W. Mitzel 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 105 KB

The synthesis and X-ray crystal structure determination of a novel metal-terphenyl derivative, namely DmpAuPPh 3 (1), is reported (Dmp = 2,6-dimesitylphenyl). Complex 1 is synthesized by the reaction of one equivalent of DmpLi with one equivalent of Ph 3 PAuCl in tetrahydrofuran at room temperature