Origins of ฯ-face selectivity in the ald
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Anna Vulpetti; Anna Bernardi; Cesare Gennari; Jonathan M. Goodman; Ian Paterson
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Article
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1993
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Elsevier Science
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French
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A molecular mechamcs translhon state model 1s used to analyse the stereoselechvlty of a sene~ of aldol reacbons of E-en01 bormates of type 3 wth aldehydes The model reproduces the sense and degree of x-face selectlvlty for the choral E-enol bormates 8,11,13 and 14 m the Table Enolates 8 and 10 prefe