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Origins of stereoselectivity in chiral boron enolate aldol reactions: A computational study using transition state modellings

โœ Scribed by Anna Bernardi; Anna M Capelli; Angiolina Comotti; Cesare Gennari; Mark Gardner; Jonathan M Goodman; Ian Paterson


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
884 KB
Volume
47
Category
Article
ISSN
0040-4020

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Origins of ฯ€-face selectivity in the ald
โœ Anna Vulpetti; Anna Bernardi; Cesare Gennari; Jonathan M. Goodman; Ian Paterson ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 758 KB

A molecular mechamcs translhon state model 1s used to analyse the stereoselechvlty of a sene~ of aldol reacbons of E-en01 bormates of type 3 wth aldehydes The model reproduces the sense and degree of x-face selectlvlty for the choral E-enol bormates 8,11,13 and 14 m the Table Enolates 8 and 10 prefe