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Origins of conformational equilibrium isotope effects for hydrogen in ketones

✍ Scribed by Carolyn A. Carr; Michael J.T. Robinson; Andrew Webster

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
261 KB
Volume
30
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

The origin of conformational equilibrium
The origin of conformational equilibrium isotope effects for carbon
✍ Carolyn A. Carr; Michael J.T. Robinson; David J. Young πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 273 KB

Conformational equilibrium isotope effects for carbon are dominated by orbital interactions between C-C bonds and strong acceptor (the K\* in C=O) or strong donor (the nonbonding electrons on 0) groups, and show a small dependence upon solvent polarity. Conformational equilibrium isotope effects (CE