✦ LIBER ✦

Origin of the variation with vibrational and rotational state of the fine-structure constants in O2, SO and S2

✍ Scribed by F.D. Wayne

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 534 KB
Volume: 31
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)80066-2

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✦ Synopsis

Calculations of the spin-orbit put Aso of the fine-smcture parameter h have been performed at several internuclear distances for the molecules 02, SO end S2 in their ground (X3 C-) states. Only the interaction with the lowest r E+ state was considerad and two-centrc integrals were neglected. A,, is found to m&e the dominant contribution to k. TIC vniation of the matrix elements in ?,so with internuclear distance has been derived and when combined with espressions for the variation of the energy denominator in As, enables the coefficients for the vibrational and rotational dependence of A to be estimated. Excellent ayeement with experiment is found.

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