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Origin of the size-dependent fluorescence blueshift in [n]cycloparaphenylenes

โœ Scribed by Camacho, Cristopher ;Niehaus, Thomas A. ;Itami, Kenichiro ;Irle, Stephan


Book ID
120168680
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
669 KB
Volume
4
Category
Article
ISSN
2041-6520

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Size-dependent collisional incorporation
โœ Paul J. Campagnola; Donna M. Cyr; Mark A. Johnson ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 632 KB

We report a rapid increase in the propensity of D,O molecules to incorporate into (H,O); clusters upon collisions between D,O and a distribution of (H\*O);, 6< n c 25, clusters. We interpret this effect by invoking a size-dependent associative electron detachment cross section which increases rapidl