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Origin of Regioselectivity in the Reactions of Nitronate and Enolate Ambident Anions

โœ Scribed by Sakata, Tomomi; Seki, Natsuko; Yomogida, Kozue; Yamagishi, Hiroko; Otsuki, Akino; Inoh, Chie; Yamataka, Hiroshi


Book ID
126936563
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
516 KB
Volume
77
Category
Article
ISSN
0022-3263

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ne o&wed substituent-dependent regioseiectiviLy f&Z-vs I,l-additionl iir the &cmphil& ma&~~ of antbiaknt imines 1-3 B mtioMl& undemood &Y the relative m@fnitude of the LUMO coelpriena of the Mnes. We have recently reported the succemful chiral ~g~-m~a~ ~~ 1,2-and l,~a~tion reactions of organolithium