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Origin of enhanced rate in the platinum-catalysed enantioselective hydrogenation of methyl pyruvate

✍ Scribed by G. Bond; P.A. Meheux; A. Ibbotson; P.B. Wells

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
508 KB
Volume
10
Category
Article
ISSN
0920-5861

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New data in the enantioselective hydrogenation of ethyl pyruvate on Pt-cinchona chiral catalyst using continuous-flow fixed-bed reactor system: The origin of rate enhancement
✍ György Szöllősi; Szabolcs Cserényi; Katalin Balázsik; Ferenc Fülöp; Mihály Bartó 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 746 KB

The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenation experiments were carried out in a continuousflow