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Origin of Byproducts during the Catalytic Autoxidation of Cyclohexane

✍ Scribed by Peeters, Jozef; Jacobs, Pierre A.; Hermans, Ive


Book ID
111869186
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
144 KB
Volume
112
Category
Article
ISSN
1089-5639

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## Abstract In this work, a complementary experimental and theoretical approach is used to unravel the formation of byproducts in the autoxidation of cyclohexane. The widely accepted vision that cyclohexanone would be the most important precursor of undesired products was found inconsistent with se

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## Abstract Tracer experiments involving autoxidation of dilute solutions of inactive cyclohexanol and inactive cyclohexanone in ^14^C‐labeled cyclohexane have shown that a number of byproducts such as butanol, pentanol, butyric acid, valeric acid, caproic acid, and ϡ‐hydroxycaproic acid are to a l