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Orientational behavior of C70 molecules in chlorobenzene

โœ Scribed by Igor V. Rubtsov; Dmitrii V. Khudiakov; Alexander P. Moravskii; Victor A. Nadtochenko

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
257 KB
Volume
249
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The orientational behavior of C70 singlet excited molecules in a chlorobenzene solution has been measured at room temperature by the picosecond transient grating technique. A two-stage decay signal was observed: a fast part (~-= 12 + 5 ps) which is comparable with the corresponding signal of C6o in chlorobenzene (r = 8 _ 2 ps), and a slow part (~-= 30 + 5 ps). The data obtained are analyzed in terms of the rotation of C7o molecules. The influence of the dielectric friction on the C7o rotation is reported.

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