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Orientation of the Mn(II)−Mn(III) Dimer Which Results from the Reduction of the Oxygen-Evolving Complex of Photosystem II by NO: An Electron Paramagnetic Resonance Study †

✍ Scribed by Hanley, Jonathan; Sarrou, Josephine; Petrouleas, Vasili


Book ID
126798990
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
89 KB
Volume
39
Category
Article
ISSN
0006-2960

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Metal and ligand hyperfine couplings of a previously suggested, energetically feasible Mn(4)Ca model cluster (SG2009(-1)) for the S(2) state of the oxygen-evolving complex (OEC) of photosystem II (PSII) have been studied by broken-symmetry density functional methods and compared with other suggested