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Orientation of precrystallized poly(ethylene terephthalate)

✍ Scribed by S. A. Jabarin


Publisher
Society for Plastic Engineers
Year
1991
Tongue
English
Weight
624 KB
Volume
31
Category
Article
ISSN
0032-3888

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✦ Synopsis


Abstract

The orientation characteristics of crystalline poly(ethylene terephthalate), PET, were studied as a function of degree of crystallinity, orientation temperature, and stretch ratio. Oriented samples were analyzed with respect to mechanical, shrinkage, and barrier properties. The results show that (a) significant impact property improvement can be achieved by orienting crystallized PET, (b) the modulus, ultimate strength, and yield stress increase with orientation of precrystallized PET, (c) the initial degree of crystallinity can affect the strain‐hardening properties of PET, and (d) the total amounts of shrinkage and shrinkage stress of stretched PET increase with increasing amounts of crystallinity before orientation.


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The solubilities of nitrogen, oxygen, argon, methane, and carbon dioxide in thin films of crystalline oriented poly(ethy1ene terephthalate) in the glassy state were studied by the static sorption method. High pressure sorption isotherms were obtained for carbon dioxide. Results indicate that, above