Orientation of Lipid Spin Labels in Lecithin Multilayers
β Scribed by L. J. Libertini, A. S. Waggoner, P. C. Jost and O. H. Griffith
- Book ID
- 123649237
- Publisher
- National Academy of Sciences
- Year
- 1969
- Tongue
- English
- Weight
- 274 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0027-8424
- DOI
- 10.2307/59575
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In egg lecithin-water lamellar phases, spin-labeled stearic acid gives two superimposed ESR spectra which are only well resolved when the temperature is greater than 30 degrees C. These two spectral components are attributed to the dissociated and non-dissociated forms of the fatty acid carboxylic g
A series of de novo synthesised peptides including the artificial rigid paramagnetic amino acid TOAC at two positions with different distances from two to seven in the primary structure have been investigated by 9-and 94-GHz EPR spectroscopy under solid-state conditions. From simulations of the spec
A moment method is proposed for the analysis of the spin label spectra of oriented !ecithin bilayers. Information on the orientationd disorder of the labels can thus be obtained very simply; cxFerimentnl results are given as illustra~ tion.