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ORIENTATION IN THE FRIES REARRANGEMENT OF PHENYL CAPRYLATE

โœ Scribed by RALSTON, A. W.; McCORKLE, M. R.; SEGEBRECHT, E. W.


Book ID
120303016
Publisher
American Chemical Society
Year
1941
Tongue
English
Weight
824 KB
Volume
06
Category
Article
ISSN
0022-3263

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Para-selective fries rearrangement of ph
โœ Colin S. Cundy; Raymond Higgins; Sarah A.M. Kibby; Barrie M. Lowe; R. Michael Pa ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

The Fries rearrangement of phenyl acetate is catalysed by acidic zeolites such as H-Nu-2 and H-ZSM-5, with selectivities of 2-6:l in favout of para-substituted products. The Fries rearrangement of phenyl esters affords a mixture of o-and phydroxyphenylketones, together with phenol as a hydrolysis p