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Orientation-Controlled Monolayer Assembly of Zeolite Crystals on Glass Using Terephthaldicarboxaldehyde as a Covalent Linker

✍ Scribed by Goo Soo Lee; Yun-Jo Lee; Kwang Ha; Kyung Byung Yoon

Book ID
104202843
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
112 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐGlass plates and pseudo hexagonal prismatic ZSM-5 crystals tethered with 3-aminopropylsilyl (APS) groups, respectively, were prepared by treating them with 3-aminopropyltriethoxysilane. Subsequent treatment of the APS-tethering glass plates with terephthaldicarboxaldehyde led to facile assembly of benzaldehyde (BA) units over the glass plates via imine (±CHvN±) linkages. When the BA-tethering glass plates and the APS-tethering zeolite crystals were allowed to contact in boiling toluene, the ZSM-5 crystals strongly adhered onto the glass plates in the form of closely packed monolayers with perfect one-dimensional orientation.

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