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Orientation and Protein−Cofactor Interactions of Monosubstituted n -Alkyl Naphthoquinones in the A 1 Binding Site of Photosystem I

✍ Scribed by Pushkar, Yulia N.; Zech, Stephan G.; Stehlik, Dietmar; Brown, Sarah; van der Est, Art; Zimmermann, Herbert


Book ID
127205758
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
122 KB
Volume
106
Category
Article
ISSN
0022-3654

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A possible calcium binding site in D1pro
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A peptide ranging from residue 229 to 240 of the D1 protein of Photosystem (PS) II was synthesized and lanthanides were used as candidates of calcium. Fluorescence and FTIR spectroscopy were used to test the conformational adaptation after lanthanide additions. Fluorescence spectroscopy showed that