## Abstract Organostibine‐mediated controlled/living radical polymerization of MMA was successfully achieved in room temperature ionic liquids (RTILs) [bmim]Tf~2~N and [bmim]PF~6~. The ln([M]~0~/[M]) increased linearly with increasing reaction time. The number‐average molecular weights of PMMA incr
✦ LIBER ✦
Organostibine mediated controlled/living random copolymerization of styrene and methyl methacrylate
✍ Scribed by Qiang Zhang; Jun Li; ZhengPing Liu; Yi Ni
- Book ID
- 107349268
- Publisher
- SP Science China Press
- Year
- 2010
- Tongue
- English
- Weight
- 591 KB
- Volume
- 53
- Category
- Article
- ISSN
- 1674-7291
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## Abstract Chain transfer constants to monomer have been measured by an emulsion copolymerization technique at 44°C. The monomer transfer constant (ratio of transfer to propagation rate constants) is 1.9 × 10^−5^ for styrene polymerization and 0.4 × 10^−5^ for the methyl methacrylate reaction. Cro
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