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Organosilylation: Synthesis and characterization of silylmethyl methyl ether

โœ Scribed by R. Varma


Book ID
107768519
Publisher
Elsevier Science
Year
1970
Weight
180 KB
Volume
6
Category
Article
ISSN
0020-1650

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Total synthesis of (ยฑ)-shonanyl methyl e
โœ Manuka Ghosal; Sukanta Bhattacharyya; Debabrata Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 156 KB

An efficient reductive methylation of the tricyclic ketone 12 in anhydrous ammonia provided the 8 ,y-unsaturated ketone 15 in high yield which was subsequently converted into (i)-shonanyl methyl ether 12) and (+I-ferruginylmethyl ether (5). Shonanol, a tricyclic diterpene, was isolated from Liboced