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Organosilicon-mediated total synthesis of the triquinane sesquiterpenes (±)-β-isocomene and (±)-isocomene

✍ Scribed by Schmidt, Arndt W.; Olpp, Thomas; Baum, Elke; Stiffel, Tina; Knölker, Hans-Joachim


Book ID
121395240
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
785 KB
Volume
8
Category
Article
ISSN
1477-0520

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📜 SIMILAR VOLUMES


ChemInform Abstract: Stereoselective Tot
✍ Arndt W. Schmidt; Thomas Olpp; Elke Baum; Tina Stiffel; Hans-Joachim Knoelker 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

The Total Synthesis of (±)-Isocomene by
✍ Wolfgang Oppolzer; Kurt Bättig; Tomas Hudlicky 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 233 KB 👁 1 views

## Abstract The racemic sesquiterpene isocomene (**1**) has been synthesized starting from 1,7‐octadien‐3‐one (**2**) in a stereoselective manner __(Scheme 2)__. In the key step **4** → **5** the C(7), C(8)‐bond was formed by an intramolecular thermal ene reaction. Further elaboration of **5** invo